After reading this paragraph:
A simpler version of this distinction might be more palatable: flip a coin infinitely many times. The probability that you flip heads every time is zero, but it isn't impossible (at least, it isn't more impossible than flipping a coin infinitely many times to begin with!).
I thought to myself, why is the probability of flipping heads every time zero? If we have a perfect coin and we flip it twice we get the probability to equal this:
$$\frac 12 \times \frac 12 = \frac 14$$
or for four flips we get this:
$$\frac 12 \times \frac 12 \times \frac 12 \times \frac 12 = \frac 1{16}$$
So as we approach an infinite amount of coin flips, the probability gets smaller and smaller, but it shouldn't ever reach zero, so the probability shouldn't be zero, it should be $1/+\infty$. Does this mean that $1/+\infty$ equals zero or have I misunderstood the question?
Some of the answers so far have claimed that it is not possible to make sense of flipping a coin infinitely many times. In mathematics, this is not true; there is a perfectly well-defined mathematical model (a probability space) of what it means to flip a coin infinitely many times. This model has the following properties:
From this the probability of only flipping heads is uniquely determined: it is at most the probability of flipping $N$ heads first for every positive integer $N$ (so at most $\frac{1}{2^N}$), and it is a non-negative real. The only non-negative real with this property is $0$ by the Archimedean property of the reals. So the probability of only flipping heads must be $0$.
One can think of this argument as computing a limit via the monotone convergence theorem for sets, but it is computing something slightly more basic, namely an infimum. In any case, $\frac{1}{\infty}$ is not a probability because it is not a real number.