I know that every vector in a tensor product $V \otimes W$ is a sum of simple tensors $v \otimes w$ with $v \in V$ and $w \in W$. In other words, any $u \in V \otimes W$ can be expressed in the form$$u = \sum_{i=1}^r v_i \otimes w_i$$for some vectors $v_i \in V$ and $w_i \in W$. This follows from the proof of the existence of $V \otimes W$, where one shows that $V \otimes W$ is spanned by the simple tensors $v \otimes w$; the assertion now follows from the fact that, in forming linear combinations, the scales can be absorbed in the vectors: $c(v \otimes w) = (cv) \otimes w = v\otimes (cw)$.
My question is, is it true in general that every element of $V \otimes W$ is a simple tensor $v \otimes w$?
This is in general not true. One easy way to see this, is the following: Assume $V$, $W$ are $n$ and $m$ dimensional vector fields over the complex numbers, then it is fairly easy to show that $V\otimes W$ is isomorphic to $\mathbb{C}^{n\times m}$ with the following isomorphism $\phi: V\otimes W \rightarrow \mathbb{C}^{m\times n}$, which is defined as
$\phi(u\otimes w) := uw^{H}$ for elementary tensors and extended by linearity for all $x \in V\otimes W$.
Now due to ismorphism between both spaces, we can study the same question in $\mathbb{C}^{n\times m}$: Notice that elementary tensors $u\otimes w$ correspond to matrices $uw^{H}$, hence only of rank one. A general matrix $M\in\mathbb{C}^{n\times m}$ can be decomposed into a linear combination of rank one matrices (using SVD for example) but obviously is not corresponding to a rank one matrix. Hence transferring this property to $V\otimes W$ using the isomorphism, we see that not every element in $V\otimes W$ is an elementary tensor.