I'm trying to figure out how I can describe this relationship so that I can see if it's reflexive/irreflexive/symmetric/antisymetric/transitive
If it was b - c < 0 or something I'd easily be able to understand. But I don't see what I can say definitively about b and c in this set other than that they must be either both positive or both negative in order for the condition to be true.
No
For our relation to be an equivalence relation we need it to be reflexive which means that $(x,x) \in R$ $\forall x \in \mathbb{Z}$.
Choose $x = 0$, then $x^2 = 0 \not > 0 \therefore (0,0)\not \in R$
Now if you meant $bc \geq 0$ instead, then we actually still do not have an equivalence relation. Choose $(-1, 0), (0, 2) \in R$. If $R$ was an equivalence relation then $(-1, 2)\in R$ via transitivity. However $-1\cdot 2 \not \geq 0$ therefore $R$ cannot be an equivalence relation.