I can't come up with a single one.
The range should be the whole of the reals. The best I have is $\log(x)$ but that's only on the positive real line. And there's $f(x) = x$, but this is not strictly concave. And $-e^{-x}$ only maps to half of the real line.
Any ideas?
$$ f(x) = x-e^{-x} $$ is such a function. Since $f''(x) = -e^{-x}$ is always negative, it is strictly concave, and it's not hard to show it hits every real.
Even better, $$ f(x) = 2x -\sqrt{1+3x^2} $$ has $f''(x) = -3(1+3x^2)^{-3/2} < 0$ everywhere and the explicit inverse $f^{-1}(x) = 2x+\sqrt{1+3x^2}$, clearly defined for all $x$.
EDIT: Since it was requested in the comments, here is a plot of this function and its inverse:
Note that even though the growth rate for positive $x$ is slow, the function is asymptotically linear (with slope $2-\sqrt{3}\approx 0.268$) and thus unbounded.