Is there a mathematical constant known to be algebraic irrational, but which is unknown to be a surd (root of an integer polnyomial of degree $2$) or not ?
Is there a mathemetical constant known to be algebraic, but unknown to be rational or not ?
Irrationality proofs or transcendental proofs can be extremely difficult, so I wonder whether verifying a constant to be a surd or not, can be extremely difficult as well (even if it is known that it is algebraic and irrational).
I have not much hope concerning the second question because a number known to be algebraic can probably be proven relatively easy to be rational or irrational, but maybe I am wrong.
My answer will touch upon several things, obviously on algebraic number theory, but also on logic/discrete math/theoretical computer science. I will start by elaborating on what it means to "give a constant" and some things about algebraic numbers.
For explicitness, let's assume that we only deal with complex numbers $c\in\mathbb{C}$, i.e. I will assume that any relevant constant $c$ is described in a way, such that it is a priori clear, that it is a complex number. I assume that we have some "language" to express these numbers. This language will include
There are more ways to express complex numbers, which I like to be part of our descriptive language, e.g.
There are more accepted ways to define a complex constant e.g. case destinctions, see below. The central questions are "What do we mean by a constant? What are allowed ways to describe them?" At first this might seem trivial ("Everybody knows what a constant is. I know it, when I see it $\ldots$"). The examples above, like continued fractions and in particular the link to constructive geometry, should give some idea that this is actually not so clear.
Next I deliberate on several types of complex numbers.
I am so explicit about all this because the question mentioned surds which seem to not have a universally accepted definition in mathematics and surds are mostly informally used in high school mathematics. Look up Mathworld.
My examples will work for all three notions of surds. The above examples and explanations should give enough hints to adjust the example to slightly differing circumstances, e.g. "Is there a constant known to be constructible irrational where it is unknown whether it is quadratic irrational?"
The examples employ a famous unsolved problem the P vs. NP problem. $$ C=\begin{cases}r_2, &\text{ if P$=$NP}\\r_5, &\text{ if P$\neq$NP}\end{cases} $$ $C$ is welldefined, it is either the irrational surd $r_2=\sqrt{2}$ or the unsolvable algebraic irrational $r_5$, the real solution to $x^5-x-1=0$. In any case $C$ is algebraic irrational. But as P vs NP is unresolved it is not known whether it is a surd. $$ \tilde{C}=\begin{cases}r_1, &\text{ if P$=$NP}\\r_5, &\text{ if P$\neq$NP}\end{cases} $$ Similarly $\tilde{C}$ is algebraic, but unknown to be rational or not. This examples answers the second question.
Should at some point the P vs. NP problem be resolved then you can replace P vs. NP by some new unsolved problem. Gödel's first incompleteness theorem ensures that there will always be problems that are unresolved in a very strong sense. This remark touches more on metamathematical/phylosophical concepts, since "what mathematics is known" depends on time and is not intrinsic to math. In this sense the original question has a rather metamathematical/philosophical flavor.
I admit that these examples feel like cheating. $C$ and $\tilde{C}$ feel artificial because their possible values are well known, so the unknown quality is not linked to the values, it's linked to the (philosophically) independent problem of P vs. NP, that does not seem to have much relation to the values of $r_1, r_2$ or $r_5$. I give another example that takes this to an extreme, it should not be considered a mathematical constant, but more appropriately as a "political constant" $$ \hat{C}=\begin{cases}r_2, &\text{ if the president of the USA on 1.1.2040 is male}\\r_5, &\text{ otherwise}\end{cases} $$
Here are two examples that do not feel like cheating to me, but that will not answer the original questions. $$D=\lim\limits_{n\rightarrow\infty}\left(\sum_{k=1}^n\frac{1}{n}-\ln(n)\right)$$ is the Euler-Mascheroni constant. It is known to be a welldefined real number. It's status is completely open, it is unknown if it is rational or transcendental or anything in between. It feels less artificial than $C,\tilde{C}$ or $\hat{C}$, because its unknown quality is tied to its value.
Also consider these four zeta-values $$ \zeta(5), \zeta(7), \zeta(9), \zeta(11). $$ It is known that at least one of these four is irrational (cf. previous link). It might be that all four are irrational or even that $\overline{\mathbb{Q}}(\zeta(5),\zeta(7),\zeta(9),\zeta(11))$ has transcendence degree $4$ over $\overline{\mathbb{Q}}$, but it may as well be that three of them are rational and the remaining one quadratic irrational.
Neither $D$ nor the provided $\zeta$-values are examples in the sense of the question. But they illustrate what I mean with "less artificial".
Summary.