Let $Q\colon=\{\alpha \in Ord \mid \exists \beta \in \alpha(\beta \text{ is undefinable in } \langle\alpha,<\rangle )\}$ denote the set of all ordinal numbers which has an undefinable member.
Since there are only countable many formulae, the number of definable members in $\langle\alpha,<\rangle$ must be at most countable infinite. Thus every uncountable ordinal numbers must belong to $Q$. On the other hand, for each natural number, if it's in $\alpha$, then it must be definable, this conclusion is easy to get by induction.
So $q$, the least member of $Q$ is greater than $\omega$ but at most $\omega_1$.
My question: Is $q$ exactly $\omega_1$, or a countable one?
The standard reference to this is the paper "The Elementary Theory of Well-Ordering -- A Metamathematical Study --" by Doner, Mostowski and Tarski in Logic Colloquim '77 Ed. Macintyre, Pacholski and Paris. In particular the Corollary 46 states:
It follows that every ordinal is definable in $\omega^\omega + \gamma$ for $\gamma < \omega^\omega$. However $\omega^\omega$ is not definable in $\omega^\omega \cdot 2$. So $\omega^\omega \cdot 2 \in Q$.