The definition of path-connectedness refers to the set of real numbers, $\mathbb{R}$. (More precisely, the interval $[0,1]$) On the other hand, connectedness is defined "purely" in terms of points and sets, and does not refer to $\mathbb{R}$.
The definition of simple connectedness also heavily depends on the interval $[0,1]$, or $S^1$. So here's my question: Is there any notion which is very similar to the usual simple connectedness, but defined "purely" in terms of points and sets? If there is one, is this useful?
For many spaces, such as CW complexes, path connectedness is equivalent to connectedness. Also, the loop space of a CW complex has the homotopy type of a CW complex (this theorem of Milnor may need some extra assumptions, like finiteness, I don't know the exact statement). Thus, for CW complexes at least, simple connectedness can be defined in terms of connectedness alone : a CW complex is simply connected iff it is connected and its loop space (at some (any) point) is connected. The same then holds for higher connectivity (unless there is some finiteness hypothesis in Milnor's theorem.)