Show that despite the distribution of vector (${\xi}$, ${\eta}$), $E|{\xi}-{\eta|}\le{\frac{1}{2}}$. I was thinking about the fact that the mathematical expectation of absolute value of a random variable is an integral from 0 to + infinity of 1 minus the distribution function of the foretold random variable. But that’s all I can say right now. All suggestions are welcome
Let ${\xi}$ and ${\eta}$ have equal distribution on the interval [0;1].
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This follows from a coupling argument: by Kantorovich's duality, $$\sup_{\xi,\eta\sim\text{Unif}([0,1])}\mathsf E|\xi-\eta|=\inf_{\phi\in L^1([0,1])}\left(\int_0^1\sup_{x\in[0,1]}(\phi(x)+|y-x|)dy-\int_0^1\phi(x)dx\right).$$
Set $\phi(x)=\frac12-\left|x-\frac12\right|$, it is straightforward to check that $$\int\sup_{y\in[0,1]}(\phi(y)+|x-y|)dx-\int\phi(x)dx=\frac34-\frac14=\frac12,$$ as desired.
Addendum. We do not need the full strength of Kantorovich's duality here, what is actually needed is only $$\mathsf E|\xi-\eta|\le\int_0^1\sup_{x\in[0,1]}(\phi(x)+|y-x|)dy-\int_0^1\phi(x)dx$$ for any $\phi\in L^1([0,1])$. In this case the above inequality can be easily obtained by \begin{align} &\int_0^1\sup_{x\in[0,1]}(\phi(x)+|y-x|)dy-\int_0^1\phi(x)dx\\ =&\mathsf E\sup_{x\in[0,1]}(\phi(x)+|\eta-x|)-\mathsf E\phi(\xi)\\ \ge&\mathsf E(\phi(\xi)+|\eta-\xi|)-\mathsf E\phi(\xi)\\ =&\mathsf E|\eta-\xi|. \end{align}
The inequality does not hold when $X$ and $Y$ are not independent. Consider indeed $X$ such that $P(X=0)=P(X=1)=\frac 12$ and let $Y=1-X$, so that $X$ and $Y$ have the same distribution.
Then $E(|X-Y|) = E(|2X-1|)$ and $|2X-1|=1$ a.s, hence $E(|X-Y|)=1>\frac 12$.
If $X$ and $Y$ are independent, the identity $E(|X-Y|)=2\int_0^1 F(t)(1-F(t)) dt$ and the bound $x(1-x)\leq \frac 14$ for $x\in [0,1]$ yield $E(|X-Y|)\leq \frac 12$.