Let $\{x_k\}$ and $x^*$ be a sequence and a point in $\mathbb{R}^n$, respectively. Can we conclude that $$\lim_{k\to\infty} \mathrm{Prob}(x_k=x^*)=1$$ and $$\mathrm{Prob}(\lim_{k\to\infty} x_k=x^*)=1$$ are equivalent or that one implies the other?
I think the first one implies the second, but not vice versa since $x^*$ might not be part of the sequence.
Neither implies the other.
To see why the first does not imply the second, I'll describe a sequence of random variables defined on $\Omega = [0, 1)$. These variables will all be either $1$ or $0$ with different probabilities. I'll outline where they're $1$, and they're $0$ elsewhere.
etc. Notice the pattern; the next few variables will be $1$ on a set of
measureprobability $1/8$, and that set will shift to the right until it hits $1$; then, the next few variables will be $1$ on a set of probability $1/16$, and so on.Note that these random variables satisfy your first condition; specifically, they converge to $0$ in probability. That is,
and that $\mathbb P(X_k = 0)$ is a nondecreasing sequence that tends to $1$. However, for no fixed $a \in [0, 1)$ is it the case that $X_k(a) \to 0$, because that sequence of numbers will oscillate infinitely many times between $0$ and $1$.
As you noted, the reverse implication doesn't hold either; pick a deterministic sequence that converges to something that's not in the sequence, e.g. $x_k = 1/k$ and $x^* = 0$.