I was working on this problem here below, but seem to not know a precise or clean way to show the proof to this question below. I had about a few ways of doing it, but the statements/operations were pretty loosely used. The problem is as follows:
Show that ${\bf A}^{-1}$ exists if and only if the eigenvalues $ \lambda _i$ , $1 \leq i \leq n$ of $\bf{A}$ are all non-zero, and then ${\bf A}^{-1}$ has the eigenvalues given by $ \frac{1}{\lambda _i}$, $1 \leq i \leq n$.
Thanks.
(Assuming $\mathbf{A}$ is a square matrix, of course). Here's a solution that does not invoke determinants or diagonalizability, but only the definition of eigenvalue/eigenvector, and the characterization of invertibility in terms of the nullspace. (Added for clarity: $\mathbf{N}(\mathbf{A}) = \mathrm{ker}(\mathbf{A}) = \{\mathbf{x}\mid \mathbf{A}\mathbf{x}=\mathbf{0}\}$, the nullspace/kernel of $\mathbf{A}$.)
\begin{align*} \mbox{$\mathbf{A}$ is not invertible} &\Longleftrightarrow \mathbf{N}(\mathbf{A})\neq{\mathbf{0}}\\ &\Longleftrightarrow \mbox{there exists $\mathbf{x}\neq\mathbf{0}$ such that $\mathbf{A}\mathbf{x}=\mathbf{0}$}\\ &\Longleftrightarrow \mbox{there exists $\mathbf{x}\neq\mathbf{0}$ such that $\mathbf{A}\mathbf{x}=0\mathbf{x}$}\\ &\Longleftrightarrow \mbox{there exists an eigenvector of $\mathbf{A}$ with eigenvalue $\lambda=0$}\\ &\Longleftrightarrow \mbox{$\lambda=0$ is an eigenvalue of $\mathbf{A}$.} \end{align*}
Note that this argument holds even in the case where $\mathbf{A}$ has no eigenvalues (when working over a non-algebraically closed field, of course), where the condition "the eigenvalues of $\mathbf{A}$ are all nonzero" is true by vacuity.
For $\mathbf{A}$ invertible: \begin{align*} \mbox{$\lambda\neq 0$ is an eigenvalue of $\mathbf{A}$} &\Longleftrightarrow \mbox{$\lambda\neq 0$ and there exists $\mathbf{x}\neq \mathbf{0}$ such that $\mathbf{A}\mathbf{x}=\lambda\mathbf{x}$}\\ &\Longleftrightarrow\mbox{there exists $\mathbf{x}\neq\mathbf{0}$ such that $\mathbf{A}({\textstyle\frac{1}{\lambda}}\mathbf{x}) = \mathbf{x}$}\\ &\Longleftrightarrow\mbox{there exists $\mathbf{x}\neq \mathbf{0}$ such that $\mathbf{A}^{-1}\mathbf{A}({\textstyle\frac{1}{\lambda}}\mathbf{x}) = \mathbf{A}^{-1}\mathbf{x}$}\\ &\Longleftrightarrow\mbox{there exists $\mathbf{x}\neq \mathbf{0}$ such that $\frac{1}{\lambda}\mathbf{x} = \mathbf{A}^{-1}\mathbf{x}$}\\ &\Longleftrightarrow\mbox{$\frac{1}{\lambda}$ is an eigenvalue of $A^{-1}$.} \end{align*}