Which nonnegative distribution function on the real axis with zero mean and given standard deviation minimizes the entropy? In other words \begin{align} \min_{f\in \mathcal D'(R)} H[f] &:= -\int_{-\infty}^\infty f(x)\ln f(x)\,dx, \\ \text{with} & \\ &f(x)\ge0, \\ & \int_{-\infty}^\infty f(x)\,dx=1, \\ & \int_{-\infty}^\infty xf(x)\,dx=0, \\ & \int_{-\infty}^\infty x^2f(x)\,dx = \sigma^2. \end{align} where positive $\sigma$ is given.
My conjecture is that the minimizing distribution is $f_m(x) = \frac12(\delta(x-\sigma)+\delta(x+\sigma))$. How would one rigorous prove this, or give a counterexample?
I do not think the calculus of variation works here, unlike when maximizing the entropy. It is a corner rather than stationary point.
I think you're right that the usual ways to check optimality would fail here. This may not be completely rigorous, but here is one line of thinking...
Let's assume $f_m$ minimizes $S[f]$. One way to check is to show no local perturbation of this function will yield a smaller entropy subject to your constraints.
Your proposed solution is a discrete measure defined on $\pm \sigma$:
$$\mu = \frac12 \sum_{a \in \{\pm \sigma\}} \delta_a$$
$$S[f_m] = -\frac12\int_R \Big(\delta(x-\sigma)+\delta(x+\sigma)\Big)\ln\left(\frac12\delta(x-\sigma)+\delta(x+\sigma)\right)dx =-\int_R \ln\left(\frac12\right)d\mu$$
$$ = -\ln\left(\frac12\right) +\int_{R\setminus\{\pm\sigma\}}\ln(0)d\mu = -\ln\left(\frac12\right) + Q$$
What is $Q$? Thanks to measure theory, we can see it will be $0$ (see this and this) so...
$$S[f_m] = -\ln\left(\frac12\right)\approx .69$$
Can we do better? What if we slightly adjusted the measure:
$$\mu_{d,s} = \frac{d}{2}\left[\delta_{-s}+\delta_{s}\right]+(1-d)\delta_0\;\; 0\leq d \in (0,1), s\geq\sigma$$
For a given $\mu_{d,s}$, the variance will be $$\sum_{k \in \{\pm s, 0\}}p_kk^2 = \frac{d}{2}(-s)^2+\frac{d}{2}s^2 + (1-d)\cdot 0^2 = ds^2$$
Given that we need to keep the variance stable at $\sigma$ we can relates $s$ to the amount of probability we allocate to the non-zero atoms.
$$d\cdot s^2=\sigma^2 \implies s = \sigma\sqrt{\frac{1}{d}}$$
Now our integral shakes out to be:
$$S[f_{m,s}] = -\left[d\ln\left(\frac12 d\right)+ \left(1-d\right)\ln\left(1-d\right)\right]$$
This function is maximized at $d=\frac{2}{3} \implies H \approx 1.1,\;s=\sigma\sqrt{\frac{3}{2}} \approx 1.22$ with $\frac13$ placed at zero. So it's just a discrete distribution uniformly placing probability at $-s,0,s$
The value of this function is minimized as you approach $0$ from the right to get $\lim_{d\to 0^+} H = 0$ (as also noted in the above answer -- much more succinctly than my answer ;-P)
Therefore, your solution at $H=0.69$ is somewhere in the middle of the pack. For example, setting $d=0.1$
$$f_m=\frac{0.1}{2}\Big[\delta(x+\sigma\sqrt{10}) + \delta(x-\sigma\sqrt{10})\Big] + 0.9\delta(x) \implies H \approx 0.39 < 0.69$$