This is a small scenario that I have formulated and want to solve for the mixed strategy NE.
Players A and B take actions T or F, and the payoffs are as shown. When I try to find the mixed strategy NE and assume that utility of B when he takes either T or F should be same, I get a wrong equation.
Assuming A takes T with probability q and F with probability (1-q), I get for B to have equal payoff in choosing T or F -
q + 1/2(1-q) = q/2 + 0 => q/2 + 0.5 = q/2, which shouldn't be possible. Where is the mistake happening ? Is there any restrictions on the payoffs I can have or the NE doesn't exist in this case ?

In a Nash equilibrium, a player has to be indifferent over all the strategies they are randomizing over. So what you have shown is that there is no Nash equilibrium in which player B randomizes over their two actions properly. Indeed, T strictly dominates F for player B, so player B will always choose T.