Is it possible for irreducible polynomial $f \in Q[x]$ to have irrational multiple root?
I guess not, so I supposed to assume that my polynomial has factor $(x - a)^k$ in some extention, where $a$ is irrational, $k>1$ and come to contradiction, but I don't know what could it be.
No. The field $\mathbb{Q}$ is a perfect field: no irreducible polynomial over it has multiple roots.
To see it, recall that a polynomial $P$ has multiple roots if and only if it has a non-constant common factor with its formal derivative $P'$. Now, since $P$ is irreducible, its only factors are itself and constant polynomials. Since $P'$ has degree smaller than that of $P$, the only factors it can share with $P$ are constant polynomials.