I am having trouble applying Natural Deduction rule and solving these two questions. How do I start this.
\begin{align} \{(p\lor q)\to r\}&\vdash_{\sf ND} p\to r\\ \{p\to\neg q\leftrightarrow(r\lor s),\neg s\}&\vdash_{\sf ND} (p\land\neg q)\to r \end{align}
It oftentimes works out easiest to start by hypothesizing the antecedent or "left side" of the conditionals you want to prove. Then use the assumptions and the hypothesis to help you deduce the conclusion, and then use conditional introduction. So, if you want to prove (p→r), hypothesize p, and use p along with the assumptions given. Then deduce the consequent r. Finally use conditional introduction to get to the desired well-formed formula.