Normalization of standard deviation

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I have a question regarding standard deviation. Let me start with an example: I have response times (RT) from users, let's say

RT1 = 3s
RT2 = 5s
RT3 = 8s

I have a normalizing constant for the response time (what the response time usually should be). Let's say this constant is 4s. So we have the normalized response times:

RT1 = 3s / 4
RT2 = 5s / 4
RT3 = 8s / 4

Now I would like to calculate the standard deviation. For the standard deviation I also have a constant indicating what the standard deviation typically is.

Should I now use the normalized response times or the original response times to calculate the standard deviation and then dividing by the normalization constant for the standard deviation?

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Standard deviation scales under multiplication by a constant: if $X$ has standard deviation $\sigma$, then $cX$ has standard deviation $|c| \sigma$. So it doesn't matter whether you first calculate the standard deviation and then normalize, or first normalize and then calculate the standard deviation.