I would like to find an orthogonal basis of the zero-sum space $\mathcal{V}^{(N)}_0$, defined as the space of all $N$-dimensional real vectors $v$ such that $\sum_i v_i=0$.
That would mean finding a set of $N -1$ vectors that are both orthogonal to each other and orthogonal to $v_0=(1,1,\ldots,1)$.
I tried choosing $v_2=(-1,1,0,\ldots,0),v_3=(-1,0,1,\ldots, 0),\ldots,v_n=(-1,0,0, \ldots, 1)$. These are all orthogonal to $v_0$, but not to each other, because for instance $\langle v_2,v_3\rangle=1$.
You can apply Gram-Schmidt to your choice of vectors to obtain the orthogonal basis.