Let $R$ be a finite boolean ring. It's known that there's a boolean algebra/ring isomorphism $R\cong \mathcal P(\mathsf{Bool}(R,\mathbb Z_2))$.
I'm trying to get a feel for this. The subsets of $\mathsf{Bool}(R,\mathbb Z_2)$ should somehow correspond to elements of $R$. At first I thought of $\mathbb Z_2$ as the usual subobject classifier in the category of sets, though that didn't get me very far. Then I thought the lattice perspective might help, but the only reasonably canonical map I can think of is $r\mapsto \left\{ \phi\leq \mathrm{eval}_r \right\}$, and I don't see why this should be an iso.
What's the intuition behind this isomorphism? How could one have guessed it?
$\mathsf{Bool}(R,\mathbb{Z}_2)$ has no natural structure of boolean ring; it's just the set of ring homomorphisms from $R$ to $\mathbb{Z}_2$ (preserving the identity).
Now, what does $f\colon R\to\mathbb{Z}_2$ look like? It's a ring homomorphism, so its kernel is an ideal; it's also a maximal ideal, because $\mathbb{Z}_2$ is a field.
Therefore, if $I=\ker f$, the homomorphism is easily described: $$ f(r)=\begin{cases} 0 & \text{if $r\in I$}\\[6px] 1 & \text{if $r\notin I$} \end{cases} $$ This reduces the problem to classifying all maximal ideals in $R$. So, let $I$ be a maximal ideal and set $s=\bigvee_{r\in I}r$. Since $I$ is an ideal, $x,y\in R$ implies $x\vee y=x+y+xy\in I$. Therefore $s\in I$ (because $I$ is finite) and, by maximality, we conclude that “$r\le s$ implies $r\in I$”. Indeed, if $rs=r$ and $r\notin I$, we have $1=rx+y$, where $x\in R$ and $y\in I$; but $$ s=rsx+ys=rx+ys $$ so $rx=s+ys\in I$ and then $1\in I$, a contradiction.
In particular $I=\{r\in R: r\le s\}$. Conversely, if $s\in R$, $I_s=\{r\in R:r\le s\}$ is an ideal of $R$, which is maximal if and only if $s$ is maximal in $R\setminus\{1\}$ (a coatom).
Now prove that every element of $R$ is in a unique way the meet of pairwise distinct coatoms (the empty set of coatoms, for $1$) and you'll have the correspondence you wanted.