Suppose that two 6-sided dice are thrown $n$ times and that the sum after each throw is plotted on a histogram. Let $s_i$ be the frequency of the sum $i \in \{2, 3, \dots, 12 \}$. As $n \rightarrow \infty$, the probability that
$s_i \le s_{i+1}$ for $i \in \{2, 3, \dots, 6\}$ and $s_{i} \ge s_{i+1}$ for $i \in \{7, 8, \dots, 11\}$
approaches $1$ (because the further the sum is from $7$, the less likely it is to occur). But after only a finite number of throws, what is the probability that the above expression is true? Can this be expressed as a closed-form function of $n$?
As long as you can express a "dice pool" evaluation like this as a finite state machine with transitions determined by tuples (outcome, number of throws rolling that outcome) and keep the number of states in check, it's possible to compute the result in polynomial time of reasonable order. Here's a crude explanation of the algorithm; I'm working on a more refined explanation but it's not ready yet.
I implemented this approach as part of my hdroller Python library. You can try this computation in your browser using this JupyterLite notebook.
State transition function
By default, hdroller presents outcomes to the transition function in ascending order. Therefore, we can define the state transition like this:
Manually checking the result for 1 and 2 throws:
Denominator: 36
With a single throw, the only accepting result is if the roll is exactly 7. There are 6 ways for this to happen.
Denominator: 1296
With two throws, there are three accepting possibilities:
Total = 156 ways as computed.
Plotting
The exact chance for 500 throws takes about 4 minutes on my computer when running in JupyterLite. Results are memoized so we are not starting from scratch at each number of throws.
Unless I've made an error somewhere, the convergence to 100% chance is pretty slow by the standards of throwing physical dice.
By the time you reach 500 throws you're probably better off using statistical methods rather than exact calculation, but I'll leave that to someone more versed in that approach.