I tried to solve this problem, but I really don't know how to break the problem down into different parts so that it becomes easier.
The problem is:
Suppose $A$ is a set and $p$ a transitive and reflexive relation on A. From $p$, we can define an equivalence relation $s$ on A: $$a\, s\, b \iff a\,p\,b\, \land \, b\,p\,a$$
Using $p$ and $s$ we can define a relation $t$ on the set of equivalence classes $A/s$: $$[a]\,t\,[b] \iff \forall x \in [a]\, \forall y \in [b] \; x\,p\,y$$
Prove that $t$ partially orders $A/s$.
I’m assuming that your $A\setminus s$ is the quotient, which is normally written $A/s$.
You need to show that $t$ is reflexive, antisymmetric, and transitive. I’ll do reflexivity as an illustration.
To show that $t$ is antisymmetric, start with arbitrary $[a],[b]\in A/s$ such that $[a]\mathrel{t}[b]$ and $[b]\mathrel{t}[a]$, and show that $[a]=[b]$. Begin by translating the hypothesis that $[a]\mathrel{t}[b]$ and $[b]\mathrel{t}[a]$ into a statement about the elements of $[a]$ and $[b]$, and do the same for the desired conclusion that $[a]=[b]$. That will give you a hypothesis in terms of the known relations $p$ and $s$ that you can manipulate to get the desired conclusion.
Similarly, to show that $t$ is transitive, start with arbitrary $[a],[b],[c]\in A/s$ such that $[a]\mathrel{t}[b]$ and $[b]\mathrel{t}[c]$, and show that $[a]\mathrel{t}[c]$. As for the other two properties, begin by translating everything into statements about the members of $[a],[b]$, and $[c]$, so that you can use the known properties of $p$ and $s$.