This statement is not true if we replace $\mathbb{R}^n$ with a general metric space. We can easily construct a counterexample.
However, why is it true that in $\mathbb{R}^n$, if $B_r(x) = B_s(y)$, then $x = y, r =s$?
Intuitively, one can take a point as close as we'd like to either $x, y$. And by triangle inequality, we would get that $d(x,y)$ would approach zero, which implies that $x =y$. But I can't seem to reason about it in a more proper way.
Any help would be appreciated! Thanks in advance!
First of all, the diameter of $B_r(x)$ is $2r$. Therefore, if $B_x(x)=B_s(y)$, then $2r=2s$ and so $r=s$.
So, $B_r(x)=B_r(y)$. But if $x\neq y$, $x+r'\frac{y-x}{\|y-x\|}\in B_r(x)$ for each $r'\in(-r,r)$. But if $r'$ is close enough to $-r$, $x+r'\frac{y-x}{\|y-x\|}\notin B_r(y)$. THerefore, $x=y$.