This is Problem 4.26 on p.58 of The Theory of Algebraic Numbers by Harry Pollard and Harold G. Diamond (Dover edition).
Prove that $\left|\sqrt2-\dfrac ab\right|\geq\dfrac1{3b^2}$ for all positive integers $a,b$.
Here's what I've done so far. Split into cases:
- (i) $\dfrac ab<\sqrt2$
- (ii) $\dfrac ab>\sqrt2+\dfrac13$
- (iii) $\sqrt2<\dfrac ab<\sqrt2+\dfrac13$.
(i) I followed the method used by the authors in proving a similar result in that chapter. Let $f(x)=x^2-2$; this is the minimum polynomial of $\sqrt2$ in $\mathbb Q$ so $f\left(\sqrt2\right)=0$. By the mean-value theorem: $$\frac{f\left(\sqrt2\right)-f\left(\dfrac ab\right)}{\sqrt2-\dfrac ab}\ =\ f'(\xi)$$ for some $\dfrac ab<\xi<\sqrt2$. We have $f'(\xi)=2\xi<2\sqrt2<3$, and so $$\left|f\left(\frac ab\right)\right|\ <\ 3\left|\sqrt2-\frac ab\right|$$ But $$\left|f\left(\frac ab\right)\right|=\left|\frac{a^2}{b^2}-2\right|=\frac{|a^2-2b^2|}{b^2}\geq\frac1{b^2}$$ Hence $$\left|\sqrt2-\frac ab\right|\ \geq\ \frac1{3b^2}$$ as required.
(ii) Done immediately as $$\left|\sqrt2-\frac ab\right|=\frac ab-\sqrt2\,> \frac13\geq\frac1{3b^2}$$
(iii) This is where I'm stuck.
So I've basically done much of the hard work above and the final piece is all I need to complete the jigsaw. I would be grateful for some help. Thanks.

Do the case distinction with $1/12$ instead of $1/3$. This does not affect (i) and (iii) works in the same way as (i), since you still have $2 \xi < 3$ as $2(\sqrt{2} +1/12)<3$.
Of course, you need to reconsider (ii) then. But it is hardly more difficult, as you have $\frac{a}{b} - \sqrt{2} \ge \frac{1}{12}$ and $\frac{1}{12} = \frac{1}{3 \cdot 4^2} \ge \frac{1}{3b^2}$, except if $b=1$. Yet then if $b=1$, you have that $a/b$ is an integer so that in this case $a/b \ge 2$ and the difference is at least $1/3$ in this case too.
There may be a shorter method, but this was what came to mind.