In Chapter 27 of Pinter's "A Book of Abstract Algebra", a proof is provided for the existence of an extension field $E$ of $F$. I think the only necessary background is some framework that was omitted from the proof but provided on earlier pages:
$\sigma_c$ is the substitution function defined as $\sigma_c(a(x))=a(c)$ where $c \in E$, the extension field of $F$, which is a subfield of $E$. $\sigma_c$ has been proven to be a homomorphism.
$J_c$ (denoted as $J$ in the proof) is the kernel of $\sigma_c$ and has been demonstrated to be a principal ideal that is expressed as $J_c=\langle p(x) \rangle$, where $p(x)$ is the unique monic polynomial of lowest degree in $J_c$
$\operatorname{range} \sigma_c = \{a(c): a(x) \in F[x]\}$, and is denoted as $F(c)$
Using the fundamental homomorphism theorem, we conclude from 1,2 and 3 that $F(c) \cong F[x]/\langle p(x) \rangle$
With these established, here is the proof provided by Pinter:
I understand the majority of the proof; however, I have denoted in $\color{#c00}{red}$ two areas of the proof that have me a little confused.
Firstly, it is not immediately apparent to me that the range of $h$ is a proper subset of all cosets found in the quotient ring. Specifically, how do I know that the cosets that each element of $F$ map to do not match up $1$ to $1$ with all of the cosets found in $F[x]/\langle p(x) \rangle$?
It seems like there are obviously many different cosets that have constant polynomial representatives ...but I do not see how I know for certain that the "number" (probably not the best term) of cosets that elements from $F$ map into is "less than" (probably not the best term) the number of cosets that, in total, comprise $F[x]/\langle p(x)\rangle$. i.e. there are clearly cosets of $F[x]/\langle p(x)\rangle$ that do not have constant polynomial representatives but I do not see why.
Secondly, while I understand the construction that is taking place in the $\color{#c00}{bracketed}$ portion of the proof, I do not see the motivation to establish this. Is it just to confirm that the field $F[x]/\langle p(x) \rangle$, when interpreted from the perspective of a polynomial, is behaving like a polynomial? Also, this is the first time I have ever seen a variable itself (e.g. $J+x$) function as a root...as opposed to some constant...but I suppose this arises because $p(x)$ is known to map to $0$ when $x$ is substituted for $c$ via $\sigma_c$.
Any clarification is greatly appreciated!

Answering the first part of the OP's question...
The element (coset) $\langle p(x) \rangle + x \in F[x]/\langle p(x) \rangle$ can't be put represented by a constant polynomial.
The degree of $p(x)$ is greater than or equal to $2$ (we're looking at a non-trivial extension) and the product of $p(x)$ with any other polynomial has degree greater than or equal to $2$. Also, in general, if $g(x)$ and $h(x)$ are two polynomials
$\; \text{IF } \text{degree of } g(x) \ne \text{degree of } h(x) \text{ THEN } \text{degree of } \big[g(x) + h(x)\big] = \text{max}\big(deg(g),deg(h)\big)$
Note that the statement Basic Theorem of Field Extensions is vacuous if every polynomial in $F$ has a root - then every coset has a constant representative.
For the second part, I think we can agree that under the equivalence relation (abusing notation a bit - $J$ is not a polynomial)
$\quad (J+x)^{n} \big ( = \sum _{k=0}^{n}{n \choose k}J^{k}x^{n-k} \big ) \equiv J + x^n$
So under the equivalence relation (abusing notation a bit - $J$ is not a polynomial)
$\quad (J + a_n)(J+x)^{n} \equiv (J + a_n)(J+x^n) \equiv J +a_n x^n$
filling in some proof detail.
More to the point, if you like working with cosets, a representative for the coset $J + x$ is $0 + x = x$, and so raising the coset $J + x$ to the $n^{-th}$ power is equal to the coset $J + x^n$.
You can think of think of $J$ as one big zero. When you want to find a representative in the coset you can employ Euclidean division, dividing out your 'starter polynomial' by $p(x)$ (the big zero) to get a representation with a smaller degree than $p(x)$,
There is not much dividing you can do when the starting representative is a constant polynomial, or for that matter any polynomial with degree less than $p(x)$.