Rationalizing a purely imaginary complex number

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If $\frac{z-a}{z+a},a\in \mathbb{R}$ is a purely imaginary number and $|z|=2$, then a value of a is ___. (JEE Main 2019)

For a purely imaginary number $w$, we must have $w+\bar{w}=0$, giving us $a=2$. (This solution is standard substitution and simplification, resulting in a quadratic).

I tried it using a different method(below): $$\frac{z-a}{z+a}\times\frac{\bar{z}-a}{\bar{z}-a}=\frac{z\bar{z}-az-a\bar{z}+a^2}{z\bar{z}-a^2}=\frac{z\bar{z}-az-a\bar{z}+a^2}{|z|^2-a^2}=\frac{z\bar{z}-az-a\bar{z}+a^2}{4-a^2}$$ where in the last step we substituted $z\bar{z}=|z|^2=4, z+\bar{z}=0$$

The denominator of this expression (from the other, valid solution is zero), and hence the expression is not defined.

What was the mistake and at what step was it made?

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You expanded $(z + a)(\bar{z} - a)$ as $z\bar{z} - a^2$, when the correct expression is $z\bar{z} + a\bar{z} - az - a^2$. As the comments point out, you also wrote that $z + \bar{z} = 0$, which you can't assume, since $z$ is not necessarily purely imaginary.

In general, for problems like this, pick a value of $z$ (any value) that fits your hypothesis, and plug it in at each step; you'll see where the error happens quite easily.

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$z+\bar z \neq 0$, unless, $\bar z = -z$ (i.e. $e^{i(-Arg(z))}=e^{i(Arg(z)-\pi)}$) or in other words unless ${\frak{Re}}(z)=0$), and

$(z+a)(\bar z -a)=z \bar z+a\bar z-az-a^2\neq z \bar z-a^2$, unless $z = \bar z$ or in other words unless ${\frak{Im}}(z)=0$

Indeed the canonical multiplier for removing the imaginary part of the denominator is $\frac{\bar z + a}{\bar z + a}$

So, $$\frac{z -a}{z +a}\frac{\bar z +a}{\bar z +a}=\frac{z \bar z+az-a\bar z-a^2}{z \bar z+az+a\bar z+a^2}=\frac{z \bar z+az-a\bar z-a^2}{|z+a|^2}$$

since the purpose of your choice of multiplier was to remove the imaginary part of the denominator by undoing the rotation ($e^{iArg(z)}$) by multiplying by a number with the reverse of its argument (i.e. by $e^{-iArg(z)}$) and by taking the fast route of re-using the number you already have, in conjugate, you are multiplying the magnitude by the magnitude and thus removing the rotation but squaring the magnitude.