Are there any known cases, when there are two (or more) definite integrals, none of them having any known closed-form expression on its own, but there is still a non-trivial$^\dagger$ elementary relation connecting them (e.g. one integral is the natural logarithm of the other)?
$^\dagger$ non-trivial means we want to exclude non-interesing cases (especially, linear combinations) like one integral being twice larger then the other because its integrand is twice as large.
One such relation was posted in this question. Taking different combinations of hyperbolic functions leads to other relations of this kind.
Also, proceeding along the same lines one can obtain another quadratic relation
$$ \left(\int\limits_0^\infty\frac{\cos\alpha x^2}{x^2+1}dx\right)^2+\left(\int\limits_0^\infty\frac{\sin\alpha x^2}{x^2+1}dx\right)^2={\pi\int\limits_0^\infty\frac{e^{-2\alpha x}}{x^2+4}\left(\cos\alpha x^2+\frac2x \sin\alpha x^2\right)dx} $$