Let A be A={1,2,3}, let K be the set of all symmetric and not reflexive relations of A. Is K $$ K=\{(\phi,\phi)\quad((\phi,\phi),(1,2),(2,1))\quad ((\phi,\phi),(1,3),(3,1))\quad ((\phi,\phi),(2,3),(3,2))\quad((\phi,\phi),(1,2),(2,1),(1,3),(3,1))\quad ((\phi,\phi),(1,2),(2,1),(2,3),(3,2))\quad ((\phi,\phi),(1,3),(3,1),(2,3),(3,2))\quad ((\phi,\phi),(1,2),(2,1),(1,3),(3,1),(2,3),(3,2))\} $$
???
If $R$ is a relation not reflexive, we cannot have $(1,1),(2,2),(3,3) \in R$ together but for example you may have $(1,1) \in R$ and $(2,2),(3,3) \notin R$. Or $(1,1),(2,2) \in R$ and $(3,3) \notin R$. So if you want to list them systematically, answer should also include the relations:
$$K=\big\{\{(1,1)\},\{(2,2)\},\{(3,3)\},\{(1,1),(2,2)\},\{(1,1),(3,3)\},\{(2,2),(3,3)\},\{(1,1),(1,2),(2,1)\},\{(1,1),(1,3),(3,1)\},\{(1,1),(2,3),(3,2)\},... \big\}$$
and none of the elements of $K$ should not include $(\emptyset,\emptyset)$ since $\emptyset$ is not an element but a representation of empty set.