Given K a field, and $a,b \in K, a\ne0$, show $ax+b=0$ has only one solution.
is it possible to just say $ax=-b \rightarrow x=a^{-1}*-b$, we can multiply by $a^{-1}$ because each element has inverse.
Does this prove the linear equation has only one solution?
That's ok; but you only used one-directional implication, sp now you need to go back and check that that is a solution indeed. Without checking, what you showed is that"If the equation has a solution, then it is $-b a^{-1}$. So it's possible it has that solution, and it's also possible it has no solutions, if you don't check that that's always a solution.
Alternatively you could just replace the one-directional arrow by a bi-directional arrow and you're done.