I was doing this exercise and there is a hint to consider the Skolem functions for $L_{\omega_1}$. However, I did not find any general definition of what a Skolem function may be in Kunen (1980), and I do not know how to proceed with this hint. Any help in clarification or hint in another directions would be appreciated. Thank you.
Show that $\{\alpha<\omega_1 : L_\alpha \prec L_{\omega_1}\}$ is closed unbounded in $\omega_1$.
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For a route more similar to what Kunen is suggesting, proceed like the proof of the reflection theorem.
Let $\alpha < \omega_1.$ For a formula $\varphi(x,\vec y)$ and $\vec y \in L_\alpha,$ let $F(\alpha, \varphi, \vec y)$ be the least ordinal $\beta >\alpha$ such that there is an $x\in L_\beta$ with $L_{\omega_1}\models \varphi(x,\vec y)$ if there is any such $x\in L_{\omega_1},$ otherwise let $F(\alpha, \varphi, \vec y)=0.$ Define $$\alpha' = \sup\{F(\alpha, \varphi,\vec y): \varphi\in Form, \vec y\in L_\alpha\}.$$ Since there are countably many $\vec y$ and $\varphi,$ we have $\alpha'<\omega_1.$
Then, given an arbitrary $\alpha< \omega_1,$ let $\alpha_0 = \alpha$ and recursively let $\alpha_{n+1}= \alpha_n'$ and $\alpha^* = \lim_n \alpha_n.$
By the Tarski-Vaught test, $L_{\alpha^*}\prec L_{\omega_1}.$ Thus, the set in question is unbounded. Closure follows easily, as Noah mentions in his answer, since an increasing union of elementary submodels is an elementary submodel.
You can use Skolem functions to do this, but they're not necessary. Here's an argument I like:
First, I claim that it's enough to show unboundedness. We get this by applying two results, namely the coherence of elementary embeddings ($A\preccurlyeq C$, $B\preccurlyeq C$, and $A\subseteq B$ implies $A\preccurlyeq B$), and the nice behavior of elementary chains (if $A_i\preccurlyeq A_j\preccurlyeq C$ for $i<j<\lambda$ with $\lambda$ a limit ordinal then $A_i\preccurlyeq \bigcup_{i<\lambda}A_i\preccurlyeq C$ for all $i<\lambda$). Putting this all together we get that if $\alpha$ is a limit of $\{\beta: L_\beta\preccurlyeq L_{\omega_1}\}$ then $\alpha$ is in fact in that set.
Moreover, unboundedness itself is really all about constructing a single example with a parameter: it's enough to show that for each $a\in L_{\omega_1}$ there is an $\alpha$ such that $a\in L_\alpha\preccurlyeq L_{\omega_1}$. (Do you see why?)
So fix $a\in L_{\omega_1}$. By downward Lowenheim-Skolem we get an $M\preccurlyeq L_{\omega_1}$ with $a\in M$. Of course $M$ probably is not a level of $L$, so we aren't done yet. Instead we're going to build a sequence of structures:
$M_0=M$.
$M_{2i+1}=L_{M_{2i}\cap \mathsf{Ord}}$.
$M_{2i+2}$ is any countable elementary substructure $N$ of $L_{\omega_1}$ such that $M_{2i+1}\subseteq N$.
Basically, at odd steps we "fill in the gaps" and at even steps we "re-attain elementarity." Crucially, the even steps require the observation that $L_\alpha$ is countable whenever $\alpha$ is; this is where this argument would break down if we tried to run it for the $V$-hierarchy instead. It's a good exercise to check that no $V_\alpha$ is a proper elementary substructure of $V_{\omega_1}$:
Now let $M_\omega=\bigcup_{i\in\omega}M_i$. We clearly have that $M_\omega$ is a countable substructure of $L_{\omega_1}$ containing $a$ as an element; moreover, as a union of levels of $L$ it is itself a level of $L$, and as a union of elementary substructures of $L_{\omega_1}$ it is itself an elementary substructure of $L_{\omega_1}$. So we're done!