The tetrahedron is formed by the planes
$ y+z=0$,
$z+x=0$,
$x+y=0$, and
$x+y+z=a$
I'm not able to visualise the sides that will constitute the tetrahedron, so not able to figure out which edges will lie opposite to each other. Please help me understand the formation of the tetrahedron.
The "easy" way to visualize the tetrahedron is to do a coordinate change: $$X=z+y\\Y=z+x\\Z=x+y\\x+y+z=(X+Y+Z)/2$$ In this new coordinate system the sides are the $X=0$, $Y=0$, $Z=0$, and the plane that intersects each axis at $2a$. Your original tetrahedron is similar to this one, rotated $45^\circ$ two times