Suppose that $G$ is a finite group and view the additive group $\mathbb{Q}$ as a trivial $G$-module.
I want a concrete way of understanding why the second cohomology group $H^2(G, \mathbb{Q})$ is trivial.
A good start comes from the fact that this is the same as understanding why any central extension of $G$ by $\mathbb Q$ is (up to isomorphism) $G \ltimes \mathbb Q$, i.e., the extension splits.
Unfortunately, I cannot see why this is true and would really appreciate an explanation.
I believe that there are very general theorems/concepts from cohomology theory that could be used here, but I am looking for answers that are as concrete as possible.
You are only considering the case of trivial action, so you are trying to prove that the extension is isomorphic to the direct product $G \times {\mathbb Q}$.
Show it first for the case when $G$ is cyclic, using the divisibility of ${\mathbb Q}$. Then the required complement is just the torsion subgroup of the extension.
As you say, there are much more general results. If $M$ is an $KG$-module with $K$ a field of characteristic $0$, and $G$ is a finite group, then $H^n(G,M)=0$ for all $n \ge 1$.