I want to use the simplex algorithm.
At the first step we want to determine which variable will enter the basis. To do that we pick the smallest negative number of the last row of the simplex table.
Then we want to determine which variable will go out of the basis. For that we have to compute the last column of the simplex table, which is the column of the right side divided by the elements of the column that we picked in the previous step. We chose that the smallest positive element of that column. If there are also zero elements, is then that one the element that we pick or do we compare only the elements $>0$ ?
Suppose $a_{ij^*} \ \forall\ i$ are the elements of the chosen pivot column. And $b_{i} \ \forall\ i$ are the corresponding values of the RHS. As you said you calculate the minimum of the fractions. $b_{i}$ has to be greater or equal $0$. This is always the case if you apply the simplex algorithm correctly. And $a_{ij^*}$ has to be greater $0$. The short notation is
$\min\bigg\{\frac{b_i}{a_{ij^*}}|a_{ij^*}>0\bigg\} $
Since $b_{i}\geq 0$ it follows that $\frac{b_i}{a_{ij^*}}\geq 0$