Let $L/K$ be a finite field extension, and let $\mu_{\alpha,K}\in K[X]$ be the minimal polynomial of $\alpha\in L$.
One can easily see that $\alpha$ is a simple root of $\mu_{\alpha,K}$. Indeed, if it weren't the case, the polynomial $\mu_{\alpha,K}'\in K[X]$ would vanish at $\alpha$ but has lower degree that $\mu_{\alpha,K}$, which contradicts minimality of $\mu_{\alpha,K}$.
To go further, how would one prove that all roots $\beta$ of $\mu_{\alpha,K}$ are simple ?
Take the minimal polynomial of $\beta$, that is, $\mu_{\beta, K}$ and consider $gcd(\mu_{\alpha, K}, \mu_{\beta, K})$. That gcd has $\beta$ as a root, so it must be $\mu_{\beta, K}$. Since $\mu_{\alpha, K}$ is irreducible, $\mu_{\alpha, K}=\mu_{\beta, K}$ and we're done.