Can someone show me how I can solve this? (Step by step example with solution appreciated a lot as I am currently practicing).

EDIT: After a closer look, it looks as if this is an Isosceles Triangle (http://mathworld.wolfram.com/IsoscelesTriangle.html).
P.s. I appreciate if someone could share with me the mental of thinking when something similar appears, and show me how to solve this one, I'd just like to know since I do not remember much.
EDIT: Can someone copy my photo and mark things out, ABC etc, that would make it far more simple for me to understand and be able to follow. Thanks a lot in advance.
You have been given with the length of the arc(S), Using that and the radius and this formula below, Calculate $\theta$
$S=r\theta$, $\theta$ is the angle at the centre in radians.
So,
$25=10\times\theta$
$\theta=2.5$ radians
Or,
$\theta \approx 143^\circ$ in degrees
Now, In $\triangle OAB$ where O is the centre of the circle, the perpendicular from O will bisect $AB$, because $\triangle OAB$ is an isosceles triangle.
Let's say at C.
So, the overall Length of $$AB=AC+CB=10\times \sin 71.5^\circ+10\times \sin 71.5^\circ=18.96$$