I was just going through following link on wiki about the graph operations:
https://en.wikipedia.org/wiki/Graph_operations.
Just curious to know if there any other graph operations that are not defined in the above link. It would be kind of you to help me. Thanks a lot for helping me.
For an explicit example of a graph operation not (currently) listed on the wiki page, consider the wreath product. While usually defined for algebraic objects like groups, it's also possible to define a wreath product for graphs. The following definition can be found in [1] which goes on to further generalize the operation to a generalized wreath product.
EDITED TO ADD:
Another graph operation not currently listed on the wiki page is transitive closure. This one is a little surprising to me since this one is much more elementary than the wreath product.