I am working through Loring Tu's An Introduction to Manifolds (Second Edition). On page no. 56, he writes:
One of the most surprising achievements in topology was John Milnor’s discovery [27] in 1956 of exotic $7$-spheres, smooth manifolds homeomorphic but not diffeomorphic to the standard $7$-sphere. In 1963, Michel Kervaire and John Milnor [24] determined that there are exactly $28$ nondiffeomorphic differentiable structures on $S^7$.
I think that the first sentence states what exotic $7$-spheres are. They are smooth manifolds (i.e., topological manifolds with own maximal atlases) that are homeomorphic but not diffeomorphic to the standard $7$-sphere, where the standard $7$-sphere is the topological manifold $S^7$ with a maximal atlas.
My problem is with the second sentence. It says that there are exactly $28$ nondiffeomorphic differentiable structures on $S^7$. Nondiffeomorphic to what?
Also, a differentiable structure or maximal atlas is just a set of charts (which of course meet the requirements in the definition of a maximal atlas.) We know that a diffeomorphism of manifolds is a bijective $C^{\infty}$ map $F: N \to M$ whose inverse $F^{-1}$ is also $C^{\infty}$, where $M$ and $N$ are smooth manifolds. What is the definition of the diffeomorphism of two atlases, so that I understand what nondiffeomorphic differentiable structures mean?
Perhaps a better way to write this would be "pairwise non-diffeomorphic". This means that no two manifolds of the 28 are diffeomorphic to one another. The definition of diffeomorphism is the one you know.
Thus, there are 28 smooth manifolds, $M_1,...,M_{28}$, all homeomorphic to the 7-sphere, such that:
I hope it's clearer now.