SVD for Diagonalizing Differential Equation Systems

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It is said that only a linear system of differential equations with all real and complete eigenvalues can be decoupled by applying a spectral decomposition to its coefficient matrix.

Since the singular value decomposition is a generalization of the spectral decomposition, can the SVD be used to decouple linear systems of differential equations with some complex and/or defective eigenvalues?

For defective eigenvalues, what about a spectral decomposition where the leftmost matrix includes generalized eigenvectors?