For the function
$$f(x,y,z) := xyz - x^2 - y^2 - z^2$$
I was looking for the points where $f_x = f_y = f_z = 0$, where these denote the partial derivatives with respect to the subscripted variable. This leads to the system of 3 equations:
$$ \begin{aligned} xy-2z &= 0 \\ xz-2y &= 0 \\ yz-2x &= 0 \end{aligned} $$
It is clear that $x=0$, $y=0$, $z=0$ is one solution to this system. However, I was wondering how we find the full set of solutions for a polynomial system like this.
Using an online calculator I have found that $(2,2,2)$, $(-2,-2,2)$, $(2,-2,-2)$, $(-2,2,-2)$ are all solutions, although I wanted to see if I could see how to find these myself.
As you said, $(0,0,0)$ is the trivial solution. It's easy to prove than any other possible solution must have $x,y,z\ne0$. Therefore, you can isolate $z$ in the first equation, por instance, and replace it in the other two: $$xy-2z=0 \implies z=\frac{xy}{2} \implies \begin{cases} x\dfrac{xy}{2}-2y=0,\\y\dfrac{xy}{2} - 2x=0. \end{cases}$$ Finally, use those to conclude that there are only four solutions more: precisely, those that you found using the calculator.