We want to show that the boundary $\partial M$ of an $n-$manifold M is a closed subset of the manifold. We show that its complement $M\setminus\partial M$ is open in $M$. Indeed, each point $x \in M\setminus\partial M$ has an open neighborhood $V_x\subseteq M$ homeomorphic to $\mathbb R^n$. It remains only to show that $V_x$ lies entirely in $M\setminus \partial M$ which means that $V_x\cap \partial M=\emptyset$. Thank you for your help!
EDIT: In a manifold with boundary each point has an open neighborhood that is homeomorphic to $\mathbb R^n$ or to $\mathbb R^n_+=\{(x_1,\cdots,x_n)\in\mathbb R^n\;|\; x_n\ge 0\}$, the points who have open neighborhoods homeomorphic to $\mathbb R^n_+$ form the boundary of the manifold.