Consider the set of angles $C = [0, \ 2\pi)$ and, for all $x,y \in C$, define the $sum$ operation as the sum modulo $[0, \ 2\pi)$.
The identity element of the addition is the angle $0$. The inverse element exists.
Associativity and Commutativity hold.
I am not sure about the operation of $scalar \ multiplication$ $\cdot$.
1) Can I define the scalar multiplication (with identity element $1$) as $a \cdot x \ \text{mod } [0, \ 2\pi)$ for all $a \in \mathbb{R}$ and $x \in C$?
If so, seems that $a ( b \cdot x) = (a b) \cdot x $ for all $a,b \in \mathbb{R}$ and $x \in C$. Also seems that distributivity holds.
2) Is $(C,+,\cdot)$ a vector space then?
3) Is $(C,+,\cdot)$ metric for some distance function $d$?
It can't be a vector space because scalar multiplication doesn't behave as required. For instance, given your algebraic operations, we'd have $$\frac{1}{2} \star (2 \star \pi) = \frac{1}{2} \star 0 = 0$$ but $$\left(\frac{1}{2} \cdot 2\right) \star \pi = 1 \star \pi = \pi \ne 0$$ so scalar multiplication doesn't satisfy the necessary conditions.
To disambiguate notation I've used $\star$ for scalar multiplication, and $\cdot$ for multiplication in $\mathbb{R}$.