Suppose $X$ is a unital $C^*$-algebra, $i:X\to X^{**}$ is the natural isometric inclusion as Banach space. Denote $S_X=\{x\in X:\|x\|=1\}$, $S_{X,+}=\{x\in X:\|x\|=1,x\ge 0\}$, so does $S_{X^{**},+}$. I need to prove that $i(S_{X,+})$ is weak* dense in $S_{X^{**},+}$.
The following is my idea:
Suppose $\pi\in S_{X^{**},+}$, by Goldstein theorem, there exists a net $(x_\lambda)\subset S_{X}$ such that $i(x_\lambda)\to \pi$ weak*. Can we prove that $i(|x_\lambda|)\to \pi$ weak*?
If $X=\ell^1\Gamma$, actually, the above idea works, but I don't know whether it is correct generally.
I don't see a direct way of doing it (not saying that there isn't).
A sideways path consists using the concrete representation of $X^{**}$ as the enveloping von Neumann algebra $X''$ of $X$. The identification takes the weak$^*$-topology on $X^{**}$ to the $\sigma$-weak topology on $X'',$ and preserves positivity.
Now we have the standard result that $S_{X,+}$ is SOT-dense in $S_{X'',+}$ (see, for instance, Theorem I.7.3 in Davidson's C$^*$-Algebras By Example). This trivially implies that $S_{X,+}$ is WOT-dense in $S_{X'',+}$. Because we are working in the unit ball, the $\sigma$-weak topology agrees with the weak operator topology; so $S_{X,+}$ is $\sigma$-weak dense in $S_{X'',+}$. Finally, by the identification above, $S_{X'',+}$ corresponds with $S_{X^{**},+}$, so $S_{X,+}$ is weak$^*$-dense in $S_{X^{**},+}$.
By the way, the proof in Davidson's book, together with the argument above, show that in your notation $\pi=\lim_\lambda x_\lambda^+=\lim_\lambda |x_\lambda|$.