What are the possible values of $x$, if $\tan^{-1}x >\cot^{-1}x$?
We have $\tan^{-1}x >\cot^{-1}x\implies \tan^{-1}x -\cot^{-1}x>0 \implies \tan^{-1} x-\tan^{-1}1/x>0\implies \tan^{-1}\dfrac{x-1/x}{1-x.1/x}>0$.
What can I do now?
What are the possible values of $x$, if $\tan^{-1}x >\cot^{-1}x$?
We have $\tan^{-1}x >\cot^{-1}x\implies \tan^{-1}x -\cot^{-1}x>0 \implies \tan^{-1} x-\tan^{-1}1/x>0\implies \tan^{-1}\dfrac{x-1/x}{1-x.1/x}>0$.
What can I do now?
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Given $\displaystyle \tan^{-1}(x)>\cot^{-1}(x)\;\forall\; x\in\mathbb{R}.$
So $\displaystyle \tan^{-1}(x)>\frac{\pi}{2}-\tan^{-1}(x)$
So $\displaystyle \tan^{-1}(x)>\frac{\pi}{4}\Rightarrow x>1$
So we get $x\in(1\;,\infty).$
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A plot might help to guide the derivation.
Recall that for $x\ge0$
$$\cot^{-1}(x)=\frac{\pi}{2}-\tan^{-1}(x)$$
and hence
$$\tan^{-1}(x)>\frac{\pi}{2}-\tan^{-1}(x)$$
$$ \tan^{-1}(x)>\frac{\pi}{4}\implies x>1$$
and for $x<0$
$$\cot^{-1}(x)=-\frac{\pi}{2}-\tan^{-1}(x)$$
hence
$$\tan^{-1}(x)>-\frac{\pi}{2}-\tan^{-1}(x)$$
$$ \tan^{-1}(x)>-\frac{\pi}{4}\implies x>-1$$
therefore the solution is
$$x\in (-1,0)\cup(-1,\infty)$$
HINT:
$$\cot^{-1}x=\frac\pi2-\tan^{-1}x\implies \tan^{-1}x-\cot^{-1}x=2\tan^{-1}x-\frac\pi2>0$$