Consider $\mathbb R$ equipped with the usual Borel $\sigma$-algebra.
For each probability measure $P$ on $\mathcal B$ there exists a unique monotone, right-continuous function $F$ on $\mathbb R$ satisfying $\lim_{x\rightarrow\infty} F(x) = 1$ and $\lim_{x\rightarrow-\infty}F(x) = 0$. Conversely, for each monotone, right-continuous function $F$ on $\mathbb R$ satisfying $\lim_{x\rightarrow\infty} F(x) = 1$ and $\lim_{x\rightarrow-\infty}F(x) = 0$ there exists a unique probability measure $P$ on $\mathcal B$.
The proof for the first part defines $F(x) = P((-\infty,x])$ and shows that this function the required properties. For the second part, one defines $\mu((a,b]) := F(b) - F(a)$ and then shows that $\mu$ is a $\sigma$-finite pre-measure on the algebra of left half-open intervals. Caratheodorys extension theorem then yields a unique measure $P$ that coincides with $\mu$ on the algebra of half-open intervals.
The above procedure also works, mutatis mutandis, for left-continuous functions. Let $F^+$ and $F^-$ denote the respective right- and left-continuous functions corresponding to some probability measure $P$ on $\mathcal B$. Next, define a new function $G$ by $$G = \frac{F^+ + F^-}2.$$ Does $G$ correspond to a unique probability measure $Q$ on $\mathcal B$?
My approach: I tried to mimic the proof for the right/left-continuous case. So I defined $$\mu((a,b)) _= \frac{F^+(b) + F^+(b)}2 - \frac{F^+(a) + F^-(a)}2.$$ But the set of open intervals is not an algebra, which suggests that this idea does not work. Since we know that both $F^+$ and $F^-$ each induce a probability measure $P^+$ and $P^-$, we could simply define $P := \frac{P^+ + P^-}2$ to get a probability measure. However, is $P$ unique?
$G(x)=0$ for all but countable many $x$ and, by monotonicity, $G(x)=0$ for all $x$. So the answer is NO.
[If you meant to write $G = \frac{F^{+} +F^{-}}2$ then uniqueness follows from the fact that $G=F$ at all but countably many points and $P(a,b)$ is uniquely determined whenever $a$ and $b$ are continuity points of $F$].