Consider for definiteness the elliptic problem $$-\nabla \cdot a(x) \nabla u(x) = 0, x \in \Omega$$ with boundary conditions $u|_{\partial \Omega} =0 $, where $\Omega$ is some bounded $C^1$ domain in $\mathbb{R}^n$ and $a \in L^\infty(\Omega).$ The usual results says the only solution in $H^1(\Omega)$ is the zero function. More generally though, we can interpret the above equation distributionally for $u \in W^{1,1}(\Omega)$. The question then is whether there exists a non-zero solution to the above problem for $u \in W^{1,1}_0(\Omega)$?
This question can be thought of as asking for a "true" uniqueness result for elliptic problems. $W^{1,1}(\Omega)$ is the largest space which (to me at least) allows a natural interpretation of the above boundary value problem, hence is a natural setting for asking the question of uniqueness.
The problem above does not have a unique solution in $W^{1,1}(\Omega)$. A non-trivial solution was given by James Serrin in [A] (below).
There is an extensive theory of existence, uniqueness and non-uniqueness of weak solutions for the corresponding non-homogeneous problem: $$(*)\qquad \qquad -\mathrm{div}(a \nabla u)=f,$$ which can help understand why the problem is not an easy one. The source $f$ is usually chosen in Lebesgue spaces ($L^p$) or Marcinkiewicz spaces ($L^{p,\infty}$). Marcinkiewicz spaces are occasionally considered more natural, since the fundamental solution to $\Delta u = \delta_0$ ($n\geq 3$) has characteristic growth in a Marcinkiewicz space, but not in any Lebesgue space.
It turns out that the uniqueness of solutions to $(*)$ can fail depending on the summability of $f$. For example:
This problem led to the introduction of so-called SOLAs (Solutions Obtained as Limits of Approximations). Indeed, it turns out that the solution operator to $(*)$ mapping the source $f$ to the corresponding unique solution $u$ (for $m>(2^*)'$) is continuous even below the critical threshold $(2^*)'$, and thus one can show that SOLAs are unique:
The other possible solutions to $(*)$ with source $f$ are thus “inaccessible“ by source regularization.
[A] Serrin, James, Pathological solutions of elliptic differential equations, Annali della Scuola Normale di Pisa – Classe di Scienze, 3rd series, vol. 18 (1964), pages 385-387