I was wondering whether it makes sense to use the $\sum $ notation for uncountable indexing sets. For example it seems to me it would not make sense to say
$$ \sum_{a \in A} a \quad \text{where A is some uncountable indexing set e.g. some $A \subset \mathbb{R}$ } $$
Would it be better to avoid the above notation in general for uncountable indexing sets ? Any help in making better sense of this would be very appreciated.
It makes sense when it is given a precise definition that makes sense. If $I$ indexes a set of elements of a Hausdorff topological abelian group, then $\sum\limits_{i\in I}a_i$ can be used to denote the limit of the net of finite sums, with the finite subsets of $I$ directed by inclusion, when this limit exists.
In particular, if each $a_i$ is a nonnegative real number, then $\sum\limits_{i\in I}a_i$ exists as an element of $\mathbb R$ if and only if $\sup\left\{\sum\limits_{i\in F}a_i:F\text{ is a finite subset of }A\right\}<\infty$, and in that case $\sum\limits_{i\in I}a_i$ equals that supremum. Finiteness of this sum implies that $\{i\in I:a_i\neq 0\}$ is countable.