Consider the following definition of vector spaces:
Why are the listed conditions called "axioms"? My understanding of axioms is that they are base assumptions which are taken to be true. Thus, they're not really meant to be proven. Yet from this definition, it's necessary to show that the axioms are "satisfied" for a specific set in order to conclude that the set is a vector space. Is that somehow different than "proving" the axioms are true for the given set?

Axioms in modern mathematics means the same as a set of properties, or conditions. Different things may or may not satisfy them. When you define a vector space you are basically saying that a vector space is anything which satisfies those axioms. The axioms are not intended to have any deeper meaning than that. They simply single out some things among all by listing properties. It's simply a definition. In the olden days, some philosophers and teachers insisted on attaching some vague unverifiable truth to the notion of axiom. That is long gone (or should be).