Apologies for the less than clear question, I wasn't quite sure how to phrase it.
Say you have a random variable $X ~ N(5, 10^2)$. Say you have another random variable $Y ~ N(5, 10^2)$.
Var(2X) = 4Var(X) = 4*10^2
But:
$Var(X+Y) = Var(X) + Var(Y) = 2\times 10^2$
But now a question arises: what?! X = Y so Var(2X) = Var(X+X) = Var(X+Y) and yet two different answers are reached using the two distinct accepted formulas. How does this make any sense? What's going wrong? It shouldn't matter what we call the random variables, and yet it seems as if it does.
Because in general
$$ \mathbb{V}{\rm ar}(X + Y) = \mathbb{V}{\rm ar}(X) + \mathbb{V}{\rm ar}(Y) + \color{red}{2\operatorname{\mathbb{C}{\rm ov}}(X,Y)} $$
in your last step you missed to include the covariance of $X$ with $X$