This is relevant to the question here.
Let $\mathbb{H}$ be the quaternions and $V = \mathbb{R}^3 \subset \mathbb{H}$ the vector space of quaternions with vanishing real part. In the linked question, it was asked whether the set $S = \{x \in \mathbb{H}: x^2 = -1\}$ is finite or infinite.
Question. For each $x \in S$, how do we describe in geometric terms the map$$T_x: V \to V, \text{ }v \mapsto -xvx^{-1},$$viewed as a linear map of the Euclidean vector space $\mathbb{R}^3$?
It's just a rotation composed with a reflection. (Or just a reflection, depending on your terminology: see the last paragraph.)
$v\mapsto xvx^{-1}$ is a rotation (even though $x$ isn't a unit vector.) After all, $xvx^{-1}=\frac{x}{\|x\|}v(x^{-1}\|x\|)=\frac{x}{\|x\|}v(\frac{x}{\|x\|})^{-1}$ and $\frac{x}{\|x\|}$ is a unit vector.
The transformation $v\mapsto -v$ can be viewed in multiple ways as a rotation and a reflection. You could say that it's a rotation by $\pi$ around the $z$ axis followed by a reflection through the $x,y$ plane. (Or a rotation by $\pi$ around the $y$ axis and a reflection through the $x,z$ plane or...)
However you do it, you can combine those two initial rotations into one and then you have a single rotation followed by a reflection.
Actually depending on your terminology, you might simply call it a "reflection." Some authors use the term "reflection" to mean "orthogonal transformation with determinant $-1$". Here I was thinking of "reflection" only as a transformation of $\mathbb R^3$ with eigenvalues $\{1,1,-1\}$.