Let $\phi:U \rightarrow S \subseteq \mathbb{R}^3$ be a chart from $U \subseteq \mathbb{R}^2$ to a surface $S$. $G = g_{ij}$ be the metric matrix such that $ g_{ij} = \frac{\partial \phi}{\partial x_i} \cdotp \frac{\partial \phi}{\partial x_j}$.
What information does $G$ give us?
Edit: I have found that if two maps from the same $U$ have the same $G$ then there exists an isometry between them. However this does not increase my geometrical understanding of $G$.
Your metric matrix $G$ is also sometimes referred as the first fundamental form (for surfaces in $\mathbb{R}^{3}$), or, more generally, as metric tensor.
This matrix is used to define inner product on all the tangent planes of $S$. As you can image, defining inner product opens a huge number of applications for $G$. Knowing how to define inner product allows us to make use of the concept of orthogonality, measure angles between (tangent) vectors, to induce norm, and much, much more!
The very limited list of things you can do using $G$ includes
Let me also list a few cool properties of metric tensor: