Starting on the crossing between the equator and the Greenwich meridian (0,0), one can proceed to any point on Earth with a given longitude and latitude along a great circle.
Seen from the centre of the Earth, what is the angle from the point (0,0) to the point (longitude, latitude), along that great circle?
Let $l$ and $L$ be respectively the longitude and the latitude of a certain point on earth.
then Its coordinates will be
$$x=R\cos(L)\cos(l)$$ $$y=R\cos(L)\sin(l)$$ $$z=R\sin(L)$$
$R$ is the Earth radius. $L=\frac{\pi}{2}$ gives the northern pole with $(0,0,R)$ as coordinates.