The book A First Course in Continuum Mechanics says the rotation tensor, R, is implicit in F.
The matrix presentation of rotation is here.
However, I am interested in its tensor representation. How can you define rotation tensor R?
The question is discussed in connection with right stretch tensor U which is defined by $U = \sqrt{F^T F}$ where $F$ is the deformation gradient. It is possible that this can help to define the rotation tensor.
It takes a few steps to get to $\mathbf{R}$ given the deformation gradient $\mathbf{F}$. Here's what I would do:
1) Compute the right Cauchy-Green tensor : $\mathbf{C} = \mathbf{F}^T\mathbf{F} = \mathbf{UR}^T\mathbf{RU}=\mathbf{U}^2$. Note that $\mathbf{C}$ is a symmetric, positive-definite tensor.
2) Next compute the eigenvalues and eigenvectors of $\mathbf{C}$ (let's call them $\omega_i$ and $\mathbf{r}_i$). Recall that the eigenvectors of $\mathbf{C}$ are the same as those of $\mathbf{U}$, and that the eigenvalues of $\mathbf{U}$ are the square roots of the eigenvalues of $\mathbf{C}$.
3) Now, compute $\mathbf{U}=\sqrt{\mathbf{C}}$ by using the spectral decompotition of $\mathbf{U}$.
$$ \mathbf{U} = \sum_{i=1}^3 \sqrt{\omega_i} \left( \mathbf{r}_i \otimes \mathbf{r}_i \right) $$
4) After this, return to your polar decomposition and compute $$ \mathbf{R} = \mathbf{FU}^{-1} $$
The algebra can be a bit tedious, but once you know the process, it's pretty mechanical to get to the answer. Most continuum mechanics textbooks should have a rigorous proof of everything I just showed. One of the best I've read is called "The Mechanics and Thermodynamics of Continua". There's only one book out there by that title, so a quick search should find it.