I have written something that says along the line
"Let matrix $A\in\mathbb{R}^{n \times n}$ be "earth-shattering", and assume that $A$ is not identically zero"
What I want to express is that $A$ is not the zero matrix.
Q1: Should I simply say that $A$ is not zero?
I am not trained on proper math language, but in the back of my mind "identically zero" means "zero everywhere", which seems most appropriate when we are discussing functions.
Q2: What is the proper way to use "identically zero"? What can and what can't be "identically zero"?
You are correct - when we say something is "identically" some value, generally we are talking about a function taking on that value everywhere. So it doesn't make much sense to say that a matrix is "identically zero". Though it is possible to think of a matrix as a linear transformation, in which case you can say that the linear transformation associated with the matrix is identically zero. This is true if and only if $A$ is the zero matrix.